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Glycosidic Bond Formation in Aqueous Solution: On the Oxocarbenium Intermediate

✍ Scribed by Stubbs, John M.; Marx, Dominik

Book ID
126249203
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
112 KB
Volume
125
Category
Article
ISSN
0002-7863

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Aspects of Glycosidic Bond Formation in
Aspects of Glycosidic Bond Formation in Aqueous Solution: Chemical Bonding and the Role of Water
✍ John M. Stubbs; Dominik Marx πŸ“‚ Article πŸ“… 2005 πŸ› John Wiley and Sons 🌐 English βš– 251 KB πŸ‘ 1 views

## Abstract A model of the specific acid‐catalyzed glycosidic bond formation in liquid water at ambient conditions is studied based on constrained Car–Parrinello ab initio molecular dynamics. Specifically the reaction of α‐D‐glucopyranose and methanol is found to proceed by a D~N~A~N~ mechanism. Th