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Glycoside bond cleavage in the radiolysis of aqueous solutions of methylglycosides and disaccharides

✍ Scribed by O. I. Shadyro; R. M. Kisel’


Book ID
110164593
Publisher
SP MAIK Nauka/Interperiodica
Year
2007
Tongue
English
Weight
228 KB
Volume
41
Category
Article
ISSN
0018-1439

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## Abstract A model of the specific acid‐catalyzed glycosidic bond formation in liquid water at ambient conditions is studied based on constrained Car–Parrinello ab initio molecular dynamics. Specifically the reaction of α‐D‐glucopyranose and methanol is found to proceed by a D~N~A~N~ mechanism. Th