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Glaser Oxidative Coupling in Ionic Liquids: An Improved Synthesis of Conjugated 1,3-Diynes.

โœ Scribed by J. S. Yadav; B. V. S. Reddy; K. Bhaskar Reddy; K. Uma Gayathri; A. R. Prasad


Book ID
101951571
Publisher
John Wiley and Sons
Year
2003
Weight
104 KB
Volume
34
Category
Article
ISSN
0931-7597

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Glaser oxidative coupling in ionic liqui
โœ J.S. Yadav; B.V.S. Reddy; K.Bhaskar Reddy; K.Uma Gayathri; A.R. Prasad ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 184 KB

Terminal alkynes undergo oxidative-coupling smoothly in the presence of the CuCl-TMEDA catalytic system in hydrophobic [bmim]PF 6 ionic liquid under aerobic conditions to produce 1,3-diynes in excellent yields under mild conditions. The substrates, alkynes, show enhanced reactivity and selectivity i