𝔖 Bobbio Scriptorium
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Germylenes

✍ Scribed by N. Takeda; N. Tokitoh; R. Okazaki

Publisher
John Wiley and Sons
Year
2004
Weight
49 KB
Volume
35
Category
Article
ISSN
0931-7597

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Carbenanaloge Germylen-Komplexe
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Several synthetic methods of bifunctional germylenes GeYz (Y = RO, PhO, RS, CH3CO0, Acac; YZ = OCHZCHZO, SCHZCHZS) or GeXY (Y = RO, X = C1; Y = RS, X = CI; Y = Acac, X = Cl) such as exchange reactions, dechlorhydratation reactions and nucleophilic substitutions from GeClz . dioxane are described.

Transition Metal Complexes of N-Heterocy
Transition Metal Complexes of N-Heterocyclic Germylenes
✍ Farman Ullah; Olaf Kühl; Gabor Bajor; Tamas Veszprémi; Peter G. Jones; Joachim H 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 304 KB

## Abstract The five‐membered N‐heterocyclic germylenes (NHGe) 1a–3a, with or without benzo or naphtho anellation, react with [Mo(CO)~3~(cht)] (cht = 1,3,5‐cycloheptatriene) to form the__fac__‐[(NHGe)~3~Mo(CO)~3~] complexes 1b–3b. Similarly, [Ni(bnNHGe)~4~] was obtained from the benzo‐anellated ger