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Carbene-Analogous Germylene Complexes
✍ Scribed by Doz. Dr. Peter Jutzi; Dipl.-Chem. Wolfgang Steiner
- Publisher
- John Wiley and Sons
- Year
- 1976
- Tongue
- English
- Weight
- 242 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
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## Abstract Triphenylphosphonium trichlorogermanate was prepared in quantitative yield by reducing germanium tetrachloride‐triphenylphosphine (1:1) with tributyl‐tin hydride in diethyl ether. Heating the phosphonium salt at 245°C gave Ph~3~P‐GeCl~2~ in 90% recrystallized yield. Treatment of the pho