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Geometrical structures and probable dissociation channels of CrPm+ (m=2, 4, 6, 8) clusters
β Scribed by Xiangjun Kuang; Xinqiang Wang; Gaobin Liu
- Book ID
- 103888259
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- English
- Weight
- 676 KB
- Volume
- 405
- Category
- Article
- ISSN
- 0921-4526
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Compounds consisting of both cluster cations and cluster anions of the composition [(M 6 X 12 )(EtOH) 6 ][(Mo 6 Cl 8 )Cl 4 X 2 ] Β΄n EtOH Β΄m Et 2 O (M = Nb, Ta; X = Cl, Br) have been prepared by the reaction of (M 6 X 12 )X 2 Β΄6 EtOH with (Mo 6 Cl 8 )Cl 4 . IR data are given for three compounds. The
Bis(disulfido) bridged Nb IV cluster oxalate complexes [Nb 2 (S 2 ) 2 (C 2 O 4 ) 4 ] 4Β± were prepared by ligand substitution reaction from the aqua ion [Nb 2 (l-S 2 ) 2 (H 2 O) 8 ] 4+ and isolated as K 4 (3). The crystal structures of 1 and 2 were determined. The crystals of 1 belong to the space