Geometrical requirements for the loss of aldehyde molecules in the mass spectra of ferrocenyl esters
β Scribed by Roberts, Durward Thomas.; Little, William F.; Bursey, Maurice M.
- Book ID
- 126072722
- Publisher
- American Chemical Society
- Year
- 1967
- Tongue
- English
- Weight
- 890 KB
- Volume
- 89
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
Contrary to previous suppositions, it appears that the [C&$ produced by the loss of 2 CO from para-beruoquinones passes through the symmetry of not a substituted cyclobutadiene, but rather a substituted tetrahedrane, at least for inert R. Thep-fluoro labeling technique is used to obtain this result.
Nestive ions zue shown to lad to so!vated ions in 'he \_ms phzsse by rcsction with estew of formic acid w&n two requirements ar"-mat: (1) the bond energy of the cluster is grezter than 9.3 kczljmole, and (2) the proton nfimity of the negative ion is gcater tisn 3:9 kcaliniole. A likely mechanism for