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Geometrical confinement effect in the liquid-phase semihydrogenation of phenylacetylene over mesostructured silica supported Pd catalysts

โœ Scribed by Napaporn Tiengchad; Okorn Mekasuwandumrong; Chayanin Na-Chiangmai; Patcharaporn Weerachawanasak; Joongjai Panpranot


Book ID
116343691
Publisher
Elsevier Science
Year
2011
Tongue
English
Weight
942 KB
Volume
12
Category
Article
ISSN
1566-7367

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Impact of palladium silicide formation o
โœ Joongjai Panpranot; Kunnika Phandinthong; Terachai Sirikajorn; Masahiko Arai; Pi ๐Ÿ“‚ Article ๐Ÿ“… 2007 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 398 KB

In this study, palladium silicide was formed on the sol-gel derived SiO 2 supported Pd catalysts when they were prepared by ion-exchange method using Pd(NH 3 ) 4 Cl 2 as a palladium precursor. No other palladium phases (PdO or Pd 0 ) were evident after calcinations at 450 โ€ข C for 3 h. The Pd/SiO 2 c