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Effect of strong metal–support interaction on the catalytic performance of Pd/TiO2 in the liquid-phase semihydrogenation of phenylacetylene

✍ Scribed by Patcharaporn Weerachawanasak; Okorn Mekasuwandumrong; Masahiko Arai; Shin-Ichiro Fujita; Piyasan Praserthdam; Joongjai Panpranot

Book ID
113686589
Publisher
Elsevier Science
Year
2009
Tongue
English
Weight
830 KB
Volume
262
Category
Article
ISSN
0021-9517

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Impact of palladium silicide formation o
Impact of palladium silicide formation on the catalytic properties of Pd/SiO2 catalysts in liquid-phase semihydrogenation of phenylacetylene
✍ Joongjai Panpranot; Kunnika Phandinthong; Terachai Sirikajorn; Masahiko Arai; Pi 📂 Article 📅 2007 🏛 Elsevier Science 🌐 English ⚖ 398 KB

In this study, palladium silicide was formed on the sol-gel derived SiO 2 supported Pd catalysts when they were prepared by ion-exchange method using Pd(NH 3 ) 4 Cl 2 as a palladium precursor. No other palladium phases (PdO or Pd 0 ) were evident after calcinations at 450 • C for 3 h. The Pd/SiO 2 c