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Geometrical and energetical aspects of structure of 3,6-di-tert-butyl-o-benzoquinones

✍ Scribed by G. K. Fukin; A. V. Cherkasov; M. P. Shurygina; N. O. Druzhkov; V. A. Kuropatov; S. A. Chesnokov; G. A. Abakumov

Publisher: Springer
Year: 2010
Tongue: English
Weight: 385 KB
Volume: 21
Category: Article
ISSN: 1040-0400
DOI: 10.1007/s11224-010-9590-1

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## Abstract The reduction of 3,6‐di‐__tert__‐butyl‐__o__‐benzoquinone with tin amalgam gives the different tin catecholate complexes. The use of polar solvents for this reaction leads to the formation of Cat~2~Sn · L~2~ species (where Cat—dianion of 3,6‐di‐__tert__‐butylcatechol, L = Et~2~O, THF, P