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ChemInform Abstract: Functionalization of Sterically Hindered o-Benzoquinones: Amino-Substituted 3,6-Di(tert-butyl)-o-benzoquinones.

โœ Scribed by G. A. Abakumov; V. K. Cherkasov; T. N. Kocherova; N. O. Druzhkov; Yu. A. Kurskii; M. P. Bubnov; G. K. Fukin; L. G. Abakumova


Publisher
John Wiley and Sons
Year
2008
Weight
30 KB
Volume
39
Category
Article
ISSN
0931-7597

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The Reactions of 3,6-Di-tert-butyl-1,2-benzoquinone and 3,6-Ditert-butylcatechol with tert-Butyl Hydroperoxide. -The reaction of the title quinone (I) as well as its corresponding catechol with tert-butyl hydroperoxide in aprotic solvents results in ring oxidation accompanied by ring expansion furn