Chemiluminescence from electronitiy excited HS2 radi&s has be&n detected between 950 and 2100 nm in gas-pha;9 flow systems. The emission essentially consits of u:sequences of the I$ (Al 'A' -t x 'A") tra&iion wi& the 000 -000 lxmd origin at 1378 nm. DS2 was also studied For HSp the following spectro
Generation of the PF2(ã 4A2) radical and assignment of the PF2(ã–X) emission spectrum
✍ Scribed by Y. Zhao; D.W. Setser
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 468 KB
- Volume
- 210
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
The PF2(H 4A1) radical has been generated by flowing PFS through a dc discharge using He or Ar carrier gas. The PF# 'A*-% 'B, ) low-resolution emission spectrum has been analyzed to obtain v,,, o; , w; and some anharmonic constants. The radiative lifetime of the PF,( 8 'AZ) state is > 1.9 ms.
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