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Generation of oxazolium and thiazolium methylides by a caesium fluoride-induced desilylation reaction

✍ Scribed by Padwa, Albert; Chiacchio, Ugo; Venkatramanan, M. K.


Book ID
121386914
Publisher
The Royal Society of Chemistry
Year
1985
Tongue
English
Weight
155 KB
Volume
16
Category
Article
ISSN
0022-4936

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ChemInform Abstract: A Concise Total Syn
✍ M. IWAO; F. ISHIBASHI πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 33 KB πŸ‘ 2 views

A Concise Total Synthesis of (Β±)-cis-and (Β±)-trans-Clavicipitic Acids by Combinatorial Use of Directed Lithiation and Fluoride Ion-Induced Elimination-Addition Reaction of 1-(Triisopropylsilyl)gramine Derivatives. -The key steps in the synthesis of the title compounds (VIII) and (IX) are regioselec