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Generation of molecular complexity from aromatics: A formal total synthesis of coriolin from 6-methylsaligenin

✍ Scribed by Vishwakarma Singh; Biswajit Samanta

Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
232 KB
Volume
40
Category
Article
ISSN
0040-4039

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✦ Synopsis

Efficient creation of molecular complexity from simple precursors is one of the most desirable aspects of synthesis design. 1"2 Occasionally reactions in tandem, zΒ°'c or a cascade of reactions, 2d'e are employed to achieve this objective. Recently, the holosynthon concept has been proposed 3 to describe such reactions. In view of the recent interest in the chemistry of polyquinanes which is continuing unabated, 4.s we developed a method for rapid generation of molecular complexity from simple precursors. 8 Among various polyquinanes, coriolin 1, a triquinane metabolite of conolus consors, 7 has been a popular

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ChemInform Abstract: Generation of Molec
ChemInform Abstract: Generation of Molecular Complexity from Aromatics: A Formal Total Synthesis of Coriolin from 6-Methylsaligenin.
✍ Vishwakarma Singh; Biswajit Samanta πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 30 KB πŸ‘ 1 views

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