Generation and some reactions of the bis(trimethylsilyl)aminyl radical
β Scribed by Roberts, Brian P.; Winter, Jeremy N.
- Book ID
- 120210912
- Publisher
- The Royal Society of Chemistry
- Year
- 1978
- Tongue
- English
- Weight
- 205 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0022-4936
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The reactions of bis[bis(trimethyIsilyl)methyl]germylene (1) and the corresponding stannylene (2) with di-tert-butykliazidosilane gave N-(azidosi-1yl)germanimine (4) and the stannanimine (5) in quantitative yields. The structures have been confirmed by single-crystal X-ray diffraction. Crystal data
The decomposition of ethane sensitized by isopropgl radicals was studied in the tempera- The rate of formation of n-butane, isopentane, and 2,S-dimethyl-t,iire range of 496-548Β°K. butane were nieasrued. The expression kI/PZ1'\* was found to be log kl/kg"2(dm3'\*/n~ol"2 . see1!\*) = (3.2 f 0.4) -(54
We wish to report the generation of a hitherto unknown species, viz. methylborylene, CH3B:. The formation of methylborylene was recognized by the products it yielded on reaction with cyclohexene. Methylborylene is generated from methylboron dibromide and a suitable form of potassium, viz. the liquid