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Generation and rearrangements of oxonium ylides

✍ Scribed by Roskamp, Eric J.; Johnson, Carl R.


Book ID
126177142
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
244 KB
Volume
108
Category
Article
ISSN
0002-7863

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## Abstract Fused carbocyclic systems containing seven‐ and eight‐membered rings can be constructed from allylic ethers in a stereoselective manner by tandem carbenoid generation, ylide formation and [2,3] rearrangement. Exceptionally high yields are obtained in cases where the substrate possesses