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Generation and reactions of difluorocyclopropyl anion

✍ Scribed by Akira Shibuya; Sylke Pietz; Takeo Taguchi

Book ID: 104257550
Publisher: Elsevier Science
Year: 1997
Tongue: French
Weight: 180 KB
Volume: 38
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(97)01195-7

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✦ Synopsis

Reaction of l-trimethylsilyl-2,2-a~fluorocyclopropane detivtlive with aldehydes in the presence of a catalytic amount of TBA F (4 mol%) provides the correspondng cyclopropylcarbinols via cleavage of the carbon-silicon bond.

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