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Fluoride-catalyzed generation and reactions of 1-(p-tolylsulfinyl)vinyl anion

✍ Scribed by Cheng Hung-Chuan; Yan Tu-Hsin

Book ID: 104226643
Publisher: Elsevier Science
Year: 1990
Tongue: French
Weight: 210 KB
Volume: 31
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)94599-4

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✦ Synopsis

Fluoride-catalyzed desilylation of p-tolyl 1-(trimethylsilyl) vinyl sulfoxide in the presence of aldehydes results in modest yields of the corresponding allylic alcohols. Upon treatment with alkaline solution at O°C

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