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Generation and reactions of chiral, pyramidal, transition-metal Lewis acids, .eta.5-cyclopentadienylnitrosyl(triphenylphosphine)rhenium(1+) complexes

โœ Scribed by Fernandez, Jesus M.; Gladysz, J. A.


Book ID
126962398
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
351 KB
Volume
25
Category
Article
ISSN
0020-1669

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Reactions of monosubstituted alkenes RCH=CH, and [Re(q5-C,H5)(CH2CI,)(NO)(PPh3)]+BF; give complexes ([Re(q5-C5Hs)(CH2=CHR)(NO)(PPh,)l+BF; (la-g) in 63-99 %I yields as mixtures of (RS,SR)-and (RR,SS)-diastereoisomers ( l a (R