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Generation and Reaction of Monocarbonyliodonium Ylides: Ester Exchange of ( Z )-(β-Acetoxyvinyl)iodonium Salts with Lithium Ethoxide and Synthesis of α,β-Epoxy Ketones

✍ Scribed by Ochiai, Masahito; Kitagawa, Yutaka; Yamamoto, Shinji


Book ID
127322376
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
240 KB
Volume
119
Category
Article
ISSN
0002-7863

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✍ M. OCHIAI; Y. KITAGAWA 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 36 KB 👁 2 views

Reaction of Monocarbonyl Iodonium Ylides with Activated Imines: Stereoselective Synthesis of trans-and cis-α,β-Aziridino Ketones. -Treatment of iodonium salts (I) with lithium ethoxylate generates monocarbonyl iodonium ylides which readily undergo alkylidene-transfer reactions with activated imines.