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ChemInform Abstract: Reaction of Monocarbonyl Iodonium Ylides with Activated Imines: Stereoselective Synthesis of trans- and cis-α,β-Aziridino Ketones.

✍ Scribed by M. OCHIAI; Y. KITAGAWA

Publisher
John Wiley and Sons
Year
2010
Weight
36 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

Reaction of Monocarbonyl Iodonium Ylides with Activated Imines: Stereoselective Synthesis of trans-and cis-α,β-Aziridino Ketones. -Treatment of iodonium salts (I) with lithium ethoxylate generates monocarbonyl iodonium ylides which readily undergo alkylidene-transfer reactions with activated imines. Depending on their N-substitution pattern the aziridination can afford trans-or cis-aziridines preferentially. -(OCHIAI, M.; KITAGAWA,

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