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Generation and isomerization of cis, trans, cis-1,3,5-cyclooctatriene at 180.deg.

✍ Scribed by Baldwin, John E.; Kaplan, Mark S.


Book ID
125995944
Publisher
American Chemical Society
Year
1972
Tongue
English
Weight
368 KB
Volume
94
Category
Article
ISSN
0002-7863

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Isolation and valency isomerization of c
✍ David S. Glass; J.W.H. Watthey; S. Winstein πŸ“‚ Article πŸ“… 1965 πŸ› Elsevier Science 🌐 French βš– 274 KB

It was reported recently (3) from this Laboratory that cis-cis-cis-1,4,7-cyclononatriene I is isomerized by potassium t-butoxide (KOBu) in dimethylsulfoxide (DMSO) to the cis-cis-cis-1,3,6:isomer 11 and then to the bicyclic isomer, (4) cis-bicyclo[4. 3.O]nona-P, rl-diene IV. Although cis-cis-cis-1,3