Generation and Characterization of 1,2-Diaryl-1,1,2,2-tetramethyldisilane Cation Radicals
✍ Scribed by Guirado, Gonzalo; Haze, Olesya; Dinnocenzo, Joseph P.
- Book ID
- 127086236
- Publisher
- American Chemical Society
- Year
- 2010
- Tongue
- English
- Weight
- 985 KB
- Volume
- 75
- Category
- Article
- ISSN
- 0022-3263
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I,I,2,2-Tetramethyldisilane reacts with Fez(CO)9 to yield bis(u-dimethylsilylene)-u-car-bony1 bis(tricar-bonylironJ(Fe-Fe). Reaction with octacarbonyldicobalt analogously gives bis(u-dimethylsilylene)bis-(tricarbonylcobalt)(Co-Co) as stable product; spectroscopic results also indicate inter alia the
## Abstract The pyrolysis of 1‐aroylamino‐4,5‐diphenyl‐1,2,3‐triazoles 1 yields, pressumably __via__ the 4,5‐diphenyl‐1,2,3‐triazolyl radical (2a), 2,3‐diphenyl‐2__H__‐azirine (11a) and 2‐aryl‐4,5‐diphenylimidazoles 14 as the major products. Upon irradiation 1‐benzoylamino‐4,5‐diphenyl‐1,2,3‐triazo