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Generation, alkylation, and silylation of directed enolates formed by reaction of ketenes and organolithium reagents

✍ Scribed by Baigrie, Lynn M.; Lenoir, Dieter; Seikaly, Hani R.; Tidwell, Thomas T.

Book ID
124093705
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
689 KB
Volume
50
Category
Article
ISSN
0022-3263

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πŸ“œ SIMILAR VOLUMES

Alkylation and silylation of directed en
Alkylation and silylation of directed enolates from diethylketene and organometallic reagents
✍ Thomas T. Tidwell πŸ“‚ Article πŸ“… 1979 πŸ› Elsevier Science 🌐 French βš– 180 KB

Diethylketene and organometallic reagents form enolates capturable by methyl iodide or trimethylsilyl chloride with greater than 95% positional selectivity. Despite their multiple functionality and high reactivity ketenes have found only limited utility as laboratory scale synthetic reagents.' Inste