Generating highly polarized nuclear spins in solution using dynamic nuclear polarization
✍ Scribed by J. Wolber; F. Ellner; B. Fridlund; A. Gram; H. Jóhannesson; G. Hansson; L.H. Hansson; M.H. Lerche; S. Månsson; R. Servin; M. Thaning; K. Golman; J.H. Ardenkjær-Larsen
- Publisher
- Elsevier Science
- Year
- 2004
- Tongue
- English
- Weight
- 340 KB
- Volume
- 526
- Category
- Article
- ISSN
- 0168-9002
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## Abstract Review: 194 refs.
An extension of the Closs-Kaptein-Oosterhoff theory concerning nudeor spin polarization resulting during free radical reactions is presented. This extension is based on the Merrifield ma&l for the magnetic field dependence of triplet-triplet annihilation.
Theoretical CIDNP spectra for products formed via radical pair reactions were obtained by using the transverse Cverhauser mechanism proposed by Gloss and the further constraint that the satuzated sfates have their nuclear spin configurations properiy polarized according to the sign of the electron s