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Generalized solution of interdiffusion problem: Optimal approach for multicomponent bounded systems

✍ Scribed by Danielewski, M.; Filipek, R.


Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
797 KB
Volume
17
Category
Article
ISSN
0192-8651

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✦ Synopsis


Darken's phenomenological scheme for diffusion in binary systems is used for a description of interdiffusion in multicomponent ( r 2 2) mixtures. The mathematical model of interdiffusion in the bounded mixture (i.e., layer of finite thickness) showing constant concentration (e.g., in solid or liquid solutions) and variable diffusivity of the components is formulated. We derive, with the use of idea of generalized solution, an exact expression for the evolution of components distribution. Also, we consider an asymptotic approximation of the exact expression which can be simply applied to a variety of initial conditions. We show, in an elementary case of interdiffusion in a two-component mixture with constant diffusion coefficients, the analytical results and the complete algorithm of finding the density profiles. The experimental and theoretical results for a Cu-Ni solid solution are presented.


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