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Generalization of the classical Kramers rate for non-Markovian open systems out of equilibrium

โœ Scribed by Bolivar, A. O.


Book ID
111876175
Publisher
American Institute of Physics
Year
2008
Tongue
English
Weight
571 KB
Volume
49
Category
Article
ISSN
0022-2488

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A generalized rate law for the thermal d
โœ Heshel Teitelbaum ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 256 KB

It is shown that the standard rate law for thermal decomposition of diatomic molecules, AB, in mixtures with an inert species, M, breaks down severely under conditions of vibrational disequilibrium, even when the time scales for relaxation and dissociation