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General synthetic routes to ?-hydroxy-acids from t-butyl esters and the Reformatskii reaction

✍ Scribed by Cornforth, D. A.; Opara, A. E.; Read, G.


Book ID
115469307
Publisher
The Royal Society of Chemistry
Year
1969
Tongue
English
Weight
968 KB
Volume
0
Category
Article
ISSN
0022-4952

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The Generation of (Samarium) Thiolates from Aryl Thiocyanates and Their Reaction with Epoxides: A Route to Ξ²-Hydroxy Sulfides. -A new, efficient method of ring opening of epoxides like (I) and (V), using samarium thiolates, with good regioselectivity and under mild reaction conditions is demonstrat