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ChemInform Abstract: The Generation of (Samarium) Thiolates from Aryl Thiocyanates and Their Reaction with Epoxides: A Route to β-Hydroxy Sulfides.

✍ Scribed by I. W. J. STILL; L. J. P. MARTYN

Publisher: John Wiley and Sons
Year: 2010
Weight: 33 KB
Volume: 29
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199825114

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✦ Synopsis

The Generation of (Samarium) Thiolates from Aryl Thiocyanates and Their Reaction with Epoxides: A Route to β-Hydroxy Sulfides.

-A new, efficient method of ring opening of epoxides like (I) and (V), using samarium thiolates, with good regioselectivity and under mild reaction conditions is demonstrated. -(STILL, I. W.

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