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General synthesis of chiral borinic acid esters. Asymmetric synthesis of acyclic ketones via asymmetric hydroboration-carbenoidation

โœ Scribed by Brown, Herbert C.; Jadhav, Prabhakar K.; Desai, Manoj C.


Book ID
127195948
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
427 KB
Volume
104
Category
Article
ISSN
0002-7863

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The most effective optical isomer (lR-cis) of permethric acid --(2\_, R = H), a potent intermediate in the production of synthetic pyrethroid, was enantioselectively prepared. Certain kinds of cyclopropanecarboxylic acids are useful as acid components of synthetic pyrethroids.' Optically active form