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General Strategies for the Synthesis of the Major Classes of C -Aryl Glycosides

✍ Scribed by Kaelin, David E.; Lopez, Omar D.; Martin, Stephen F.


Book ID
125454167
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
47 KB
Volume
123
Category
Article
ISSN
0002-7863

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πŸ“œ SIMILAR VOLUMES


General entries to C-aryl glycosides. Fo
✍ Beth Apsel; John A Bender; Maya Escobar; David E Kaelin Jr.; Omar D Lopez; Steph πŸ“‚ Article πŸ“… 2003 πŸ› Elsevier Science 🌐 French βš– 190 KB

Utilizing a general entry we had developed for the synthesis of C-aryl glycosides, we have prepared the juglone derivatives 18-20 as well as the juglone precursor 13. Because 19 had been previously converted in two steps by Suzuki into galtamycinone (1), its preparation constitutes a total synthesis

A General Method for the Synthesis of C-
✍ Fuchss, Thomas ;Streicher, HansjΓΆrg ;Schmidt, Richard R. πŸ“‚ Article πŸ“… 1997 πŸ› John Wiley and Sons 🌐 English βš– 803 KB

## Abstract Methyl 2,3,4,6‐tetra‐__O__‐acetyl‐__N__‐(benzyloxycarbonyl)nojirimycin (3) can be readily transformed into the corresponding azaglycal 6 or fluoride 7, which are versatile glycosyl/piperidinosyl donors. Reaction of 7 with allyltrimethylsilane, propinyltrimethylsilane, trimethylsilyl cya