General entries to C-aryl glycosides. Formal synthesis of galtamycinone

✍ Scribed by Beth Apsel; John A Bender; Maya Escobar; David E Kaelin Jr.; Omar D Lopez; Stephen F Martin

• Book ID: 104252759
• Publisher: Elsevier Science
• Year: 2003
• Tongue: French
• Weight: 190 KB
• Volume: 44
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(02)02666-7

✦ Synopsis

Utilizing a general entry we had developed for the synthesis of C-aryl glycosides, we have prepared the juglone derivatives 18-20 as well as the juglone precursor 13. Because 19 had been previously converted in two steps by Suzuki into galtamycinone (1), its preparation constitutes a total synthesis of 1.