General Method for the Selective Functionalization of Cyclopentadienyliron Tricarbadecaboranyl Complexes via Halogenation and Sonogashira Coupling Reactions
β Scribed by Butterick, Robert; Carroll, Patrick J.; Sneddon, Larry G.
- Book ID
- 127158499
- Publisher
- American Chemical Society
- Year
- 2008
- Tongue
- English
- Weight
- 993 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0276-7333
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## Abstract A new method for the __in situ__ generation of various Ti(III) complexes is presented. CyclohexadienylβTi(IV) derivatives, which are readily prepared from the corresponding lithiated cyclohexadienes, afford the corresponding Ti(III) complexes upon thermal Cο£ΏTiβbond homolysis. The Ti(III