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General Approach for the synthesis of macroline/sarpagine related indole alkaloids Via the asymmetric pictet-spengler reaction: the enantiospecific synthesis of the Na-H, azabicyclo[3.3.1]nonone template

✍ Scribed by Yu Peng; Tao Wang; Yu Fuxiang; James M. Cook

Publisher: Elsevier Science
Year: 1997
Tongue: French
Weight: 198 KB
Volume: 38
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(97)01603-1

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✦ Synopsis

Na-H, Nb-benzyltetracyclic ketone la, a potential intermediate for the synthesis of numerous sarpagine-related alkaloids, has been synthesized enantiospecifically from D-( + )tryptophan via the asymmetric Pictet-Spengler reaction.

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