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General approach for the synthesis of macroline/sarpagine related indole alkaloids via the asymmetric Pictet-Spengler reaction: The enantiospecific synthesis of (−)-anhydromacrosalhine-methine

✍ Scribed by Tong Gan; James M. Cook

Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
195 KB
Volume
37
Category
Article
ISSN
0040-4039

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Na-H, Nb-benzyltetracyclic ketone la, a potential intermediate for the synthesis of numerous sarpagine-related alkaloids, has been synthesized enantiospecifically from D-( + )tryptophan via the asymmetric Pictet-Spengler reaction.