General acid catalysis in benzoic acid–Crystal Violet carbinol base reactions in toluene
✍ Scribed by Susanta K. Sen Gupta; Sangeeta Mishra; V. Radha Rani; Udai Arvind
- Book ID
- 112136861
- Publisher
- John Wiley and Sons
- Year
- 2012
- Tongue
- English
- Weight
- 120 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0538-8066
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## Abstract Apolar aprotic solvents are particularly advantageous for investigating the intrinsic metasubstituent effect free from complications of specific solvent effects. A kinetic study for toluene‐phase proton transfers between __meta__‐Me, F, Cl, Br, I, OMe, OPh, COPh, CF~3~, CN, NO~2~, H ben
Equilibria and kinetics of proton-transfer reactions in toluene between a set of m-and o-substituted (methyl, methoxy, chloro, nitro and hydroxy) benzoic acids and the carbinol base (colourless) of Crystal Violet were studied spectrophotometrically. The data on equilibrium and kinetic parameters wer