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Kinetics of Proton Transfer between Ortho Substituted Benzoic Acids and the Carbinol Base of Crystal Violet in Toluene. Ortho Effect on the Reactivity of Benzoic Acids in Apolar Aprotic Solvents

✍ Scribed by Sen Gupta, Susanta K.; Mishra, Sangeeta

Book ID
126993079
Publisher
American Chemical Society
Year
2011
Tongue
English
Weight
852 KB
Volume
115
Category
Article
ISSN
1089-5639

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Kinetics of proton transfer between meta
Kinetics of proton transfer between metasubstituted benzoic acids and the carbinol base of crystal violet in toluene: Specific solvent effect–free metasubstituent effect on the reactivity of benzoic acids
✍ Susanta K. Sen Gupta; V. Radha Rani πŸ“‚ Article πŸ“… 2011 πŸ› John Wiley and Sons 🌐 English βš– 128 KB πŸ‘ 1 views

## Abstract Apolar aprotic solvents are particularly advantageous for investigating the intrinsic metasubstituent effect free from complications of specific solvent effects. A kinetic study for toluene‐phase proton transfers between __meta__‐Me, F, Cl, Br, I, OMe, OPh, COPh, CF~3~, CN, NO~2~, H ben

EQUILIBRIA AND KINETICS OF REACTIONS BET
EQUILIBRIA AND KINETICS OF REACTIONS BETWEEN CARBOXYLIC ACIDS AND THE CARBINOL BASE OF CRYSTAL VIOLET IN APOLAR APROTIC SOLVENTS: RELATIVE STRENGTHS OF m- AND o-SUBSTITUTED BENZOIC ACIDS IN TOLUENE
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Equilibria and kinetics of proton-transfer reactions in toluene between a set of m-and o-substituted (methyl, methoxy, chloro, nitro and hydroxy) benzoic acids and the carbinol base (colourless) of Crystal Violet were studied spectrophotometrically. The data on equilibrium and kinetic parameters wer