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Geminate recombination of proton transfer reactions: time-resolved fluorescence study of 1-naphthol-3,6-disulfonate

✍ Scribed by A. Masad; D. Huppert

Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
539 KB
Volume
180
Category
Article
ISSN
0009-2614

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✦ Synopsis

Unlike the reversible proton recombination found in many excited-state proton transfer reactions, I-naphthol-3.6-disulfonate exhibits an almost irreversible proton recombination process. As a result of quenching through geminate recombination, the fluorescence of the unprotonated form is nonexponential. The Debye-Smoluchowski equation is used to explain the effect of geminate recombination.

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