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Geminal Acylation with Methyl-Substituted Analogues of 1,2-Bis[(trimethylsilyl)oxy]cyclobutene

✍ Scribed by Crane, Sheldon N.; Jenkins, Tracy J.; Burnell, D. Jean


Book ID
127395411
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
269 KB
Volume
62
Category
Article
ISSN
0022-3263

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ChemInform Abstract: The BF3Γ—Et2O-Cataly
✍ S. N. CRANE; D. J. BURNELL πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 42 KB πŸ‘ 1 views

The BF 3 β€’Et 2 O-Catalyzed Reaction of 1,2-Bis[(trimethylsilyl)oxy]cyclobutene and Analogues with Aromatic Ketones. -Aromatic ketones (I) and (V) undergo geminal acylation with cyclobutene (II) and its methylated analogues (VIII). Subsequent rearrangement, especially during aqueous work-up, results