Gelation of poly(vinyl alcohol)/water/dimethylformamide solutions and properties of dried films

✍ Scribed by Kazuo Yamaura; Shigeki Ideguchi; Tetsuya Tanigami

• Publisher: John Wiley and Sons
• Year: 1998
• Tongue: English
• Weight: 172 KB
• Volume: 70
• Category: Article
• ISSN: 0021-8995
• DOI: 10.1002/(sici)1097-4628(19981128)70:9<1661::aid-app3>3.0.co;2-t

✦ Synopsis

The properties of solutions for syndiotacticity-rich poly(vinyl alcohol) (s-PVA)/dimethylformamide (DMF)/water systems, the gelation of the s-PVA solutions, and the properties of the dried s-PVA gel films were examined. From the results of the dissolution temperature of the polymer, the gelation temperature of the solutions, the melting temperature of the gels, and the compressive modulus of the gels, the solubility of the polymer was the highest at DMF contents of 10 -20 vol %. The maximum dynamic tensile modulus of the drawn (ϫ18) films obtained from the dried gel films with a DMF content of 10 vol % was 54.9 GPa at 20°C. The orientation of the polymer chains in the amorphous regions was higher than that in the crystalline regions. The orientation of the polymer chains in the amorphous regions for the drawn films with a DMF content of 10 vol % was higher than that for the drawn films with a DMF content of 60 vol %. The orientation of the polymer chains in the amorphous regions was considered to play an important role in the properties of high strength and high modulus.