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Gelation of poly(vinyl alcohol) solutions at low temperatures (20 to −78°C) and properties of gels

✍ Scribed by Kazuo Yamaura; Koh-Ichi Karasawa; Tetsuya Tanigami; Shuji Matsuzawa


Publisher
John Wiley and Sons
Year
1994
Tongue
English
Weight
574 KB
Volume
51
Category
Article
ISSN
0021-8995

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Gelation of poly(vinyl alcohol)/ethylene
✍ Kazuo Yamaura; Hiroshi Kitahara; Tetsuya Tanigami 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 174 KB 👁 2 views

The melting temperature of the gels of the poly(vinyl alcohol) (PVA)/ethylene glycol (EG) system was measured. It was found that the temperature was independent of the thermal hysteresis. The apparent enthalpy of the fusion of the junction, DH, was 206 kJ/mol for a high molecular weight atactic PVA