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Gateway states and bath states in the vibrational spectrum of H+3

โœ Scribed by C. Ruth Le Sueur; James R. Henderson; Jonathan Tennyson

Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
687 KB
Volume
206
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

Vibrational band intensities are obtained from discrete variable representation calculations of eigenstates for Hf. Transitions linking highly excited states to the ground state show large variations in intensities, with gateway states corresponding to highly excited bending motion ("horseshoes") which leak intensity into the nearby bath states. It is suggested that these gateway states may be observable. Implications of these results forthe interpretation ofthe infrared predissociation spectra of H:are discussed.

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