Time dependent thermal lensing has been used to monitor energy transfer from CS 2 (optically excited at 31250 cm-1 ) to Kr gas at 50-600 Tort. The results show that the energy transferred per collision is significantly more efficient at lower collision frequencies: a memory effect. This can be expla
Gateway Modes in the Collisional Energy Transfer from Highly Vibrationally Excited CS 2
✍ Scribed by Lendvay, György
- Book ID
- 126033591
- Publisher
- American Chemical Society
- Year
- 1997
- Tongue
- English
- Weight
- 167 KB
- Volume
- 101
- Category
- Article
- ISSN
- 1089-5639
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📜 SIMILAR VOLUMES
Values for (AEduwn), the average downward energy transferred from the reactant to the bath gas upon collision, have been obtained for highly vibrationally excited undeuterated and per-deuterated isopropyl bromide with the bath gases Ne, Xe, C,H,, and C,D,, a t ca. 870 K. The technique of pressure-de
The average downward collisional energy transfer () is obtained for highly vibrationally excited tert-butyl chloride, both undeuterated and per-deuterated, with Kr, N,, C02, and C2H4 bath gases, at ca. 760 K. Data are obtained using the technique of pressure-dependent very low-pressure pyrolysis. Re
The average downward energy transfer ((A Ed,,,)) is obtained for highly vibrationally excited acetyl chloride with Ne and C,H, bath gases at ca. 870 K. Data are obtained by the technique of very low-pressure pyrolysis (VLPP). Fitting these data by solution of the appropriate reaction-diffusion integ