Collisional Energy Transfer from Highly Vibrationally Excited Radicals Is Very Efficient
β Scribed by Wilhelm, Michael J.; Nikow, Matthew; Smith, Jonathan M.; Dai, Hai-Lung
- Book ID
- 126909521
- Publisher
- American Chemical Society
- Year
- 2012
- Tongue
- English
- Weight
- 907 KB
- Volume
- 4
- Category
- Article
- ISSN
- 1948-7185
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π SIMILAR VOLUMES
The average downward energy transfer ((A Ed,,,)) is obtained for highly vibrationally excited acetyl chloride with Ne and C,H, bath gases at ca. 870 K. Data are obtained by the technique of very low-pressure pyrolysis (VLPP). Fitting these data by solution of the appropriate reaction-diffusion integ
Time dependent thermal lensing has been used to monitor energy transfer from CS 2 (optically excited at 31250 cm-1 ) to Kr gas at 50-600 Tort. The results show that the energy transferred per collision is significantly more efficient at lower collision frequencies: a memory effect. This can be expla