Quantitative separation of halonitrobenzenes, anisoles and toluenes was studied on polyethyleneglycol, polyethyleneglycol succinate, polyoxyethylenesorbitan monostearate, silicone oil and squalane as liquid phases. The interactions and forces that affected the separation of the isomers and their elu
Gas—liquid chromatography of disubstituted benzene isomers : I. Separation and study of the dichlorobenzenes
✍ Scribed by Albertine E. Habboush; Adnan H. Tameesh
- Publisher
- Elsevier Science
- Year
- 1970
- Tongue
- English
- Weight
- 526 KB
- Volume
- 53
- Category
- Article
- ISSN
- 1873-3778
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✦ Synopsis
Dicl~lorobenzene isomers were scpxated on scIualane, silicone oil, polyethylcneglycol, polyoxyethylenesorbitan monostearate and polyetl~ylene~lycol succinate. Types of interactions and forces which affected the specific retention volumes and elution orders were discussed. Thermodynamic quantities were calculated and studied on squkne and polyetllyleneglycol.
Polyesters were selective for the separation of these isomers.
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From measurement and analysis of specific retention volumes of four pairs of nzeta and para isomers at four well controlled temperatures in the liquid-crystalline stationary phase p,p'-dihexoxyazoxybenzene, precise solute free energy, enthalpy and entropy parameters are obtained. It is found that th
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