Gas-phase thermolysis of crotyl allyl and crotyl propargyl sulfides
✍ Scribed by Martin, G. ;Martinez, H. ;Suhr, H.
- Book ID
- 112685793
- Publisher
- Springer
- Year
- 1987
- Tongue
- English
- Weight
- 226 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0133-1736
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract The title amines have been pyrolyzed in a stirred‐flow reactor, at temperatures of 360–500°C, pressures of 7–16 torr, and residence times of 0.5–2.9 s, using toluene as carrier gas. The reaction products were allene, propene, and the corresponding imines. The ratio allene:propene varied
The pyrolyses of four alkyl allyl sulfides with substituents on the a-C atom of the alkyl moiety have been studied in a stirred-flow system over the temperature range 340-400°C and pressures between 2 and 12 torr. The only products formed are propene and thioaldehydes. The reactions showed first-ord
## Abstract The pyrolysis of __n__‐propyl allyl sulfide has been studied in static and stirred‐flow systems at temperatures between 270 and 400°C. Propene and 2,4,6‐triethyl‐1,3,5‐trithiane were the only reaction products. The order of the reaction was 0.99 ± 0.05 at 377°C. The first‐order rate coe