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Gas phase thermolysis of acetonyl allyl sulfide

โœ Scribed by Martin, G. ;Ropero, M.

Book ID
112683833
Publisher
Springer
Year
1983
Tongue
English
Weight
176 KB
Volume
22
Category
Article
ISSN
0133-1736

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๐Ÿ“œ SIMILAR VOLUMES

Gas-phase thermolysis of sulfur compound
Gas-phase thermolysis of sulfur compounds. Part IV. n-propyl allyl sulfide
โœ Gonzalo Martin; Marcos Ropero ๐Ÿ“‚ Article ๐Ÿ“… 1982 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 345 KB

## Abstract The pyrolysis of __n__โ€propyl allyl sulfide has been studied in static and stirredโ€flow systems at temperatures between 270 and 400ยฐC. Propene and 2,4,6โ€triethylโ€1,3,5โ€trithiane were the only reaction products. The order of the reaction was 0.99 ยฑ 0.05 at 377ยฐC. The firstโ€order rate coe

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The pyrolyses of four alkyl allyl sulfides with substituents on the a-C atom of the alkyl moiety have been studied in a stirred-flow system over the temperature range 340-400ยฐC and pressures between 2 and 12 torr. The only products formed are propene and thioaldehydes. The reactions showed first-ord