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Gas phase thermolysis of alkyl allyl ethers, thioethers and amines

✍ Scribed by Martin, G. ;Ascanio, J.

Book ID
112696910
Publisher
Springer
Year
1989
Tongue
English
Weight
189 KB
Volume
38
Category
Article
ISSN
0133-1736

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N-t-butylaniline, N-t-butyl-p-anisidine, and N-t-butyl-p-nitroaniline have been pyrolyzed in a stirred-flow reactor at 51O-62O0C, 8-15 torr total pressure, and 0.5-1.5 s contact time, using toluene as carrier gas. An order one kinetics was observed for the consumption of the amines. The reactions yi

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The pyrolyses of four alkyl allyl sulfides with substituents on the a-C atom of the alkyl moiety have been studied in a stirred-flow system over the temperature range 340-400Β°C and pressures between 2 and 12 torr. The only products formed are propene and thioaldehydes. The reactions showed first-ord