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Gas-phase structures of some hypofluorites: FOSF5, FOSO2F, FOClO3 and FONO2

✍ Scribed by Bernd Casper; Hans-Georg Mack; Heinz Oberhammer


Book ID
103183919
Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
83 KB
Volume
71
Category
Article
ISSN
0022-1139

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The reactions of some perfluoroalkyl radicals with carbon tetrachloride have been studied using the photolysis of the corresponding perfluoroalkyl iodide as the free radical source. The Arrhenius parameters, based on the value of 2.3 x 1013 cm3 mol-' s-' for the self-combination rate constant of all