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Gas-phase structures of (CF3)2S:O, (CF3)2S:NCl and (CF3)2SF2. An electron diffraction study

โœ Scribed by Oberhammer, Heinz.; Kumar, Ramesh C.; Knerr, Gary D.; Shreeve, Jean'ne M.

Book ID
126849868
Publisher
American Chemical Society
Year
1981
Tongue
English
Weight
423 KB
Volume
20
Category
Article
ISSN
0020-1669

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Rate constant ratios, k d /k c , for the disproportionation/combination reaction at a temperature of 295 ฯฎ 2 K, have been measured as 0.034 ฯฎ 0.009 for the collision between CF 3 CH 2 CF 2 ฯฉ CF 3 radicals and as 0.075 ฯฎ 0.019 for CF 3 CH 2 CF 2 ฯฉ CF 3 CH 2 CF 2 radicals. The effect of the two fluori